I’m in the same position. The networks show up, but cannot be connected to.
Systemd hardware log shows the following when trying to connect:
iwlwifi 0000:00:14.3: Not associated and the session protection is over already...
nmcli shows:
[...]
wlp0s20f3: disconnected
"Intel Alder Lake-P PCH CNVi"
3 connections available
wifi (iwlwifi), RE:DA:CT:ED:MA:CA, hw, MTU 1500
[...]
Edit: this thread seems to be making progress: Wifi stops working after sleep, after F41 upgrade - #2 by theqlp