The difficulty of accessing the kde-plasma theme store in China

Is there a mirror address, or are there other methods besides manual downloading?

Sounds like a question for the KDE folks you are over at https://discuss.kde.org/

This may require using VPN/Tor/proxy to bypass content filtering.
Note that Tor/proxy needs to be configured globally to make it work for all apps.
However, some apps still require using TUN mode to work correctly.